Everything I've read about MvR indicates that he was an OK student, and a methodical hunter, but not what we'd call a 'natural stick-and-rudder' pilot. He was, however, a very good marksman and could pull off brilliant deflection shots and frequently brought down planes with a handful of bullets.
One history of the war in the air put it this way, [paraphrased], "WWI saw three generations of pilots, or better, three successive waves. First were the Pioneers, because they were the only ones who could fly. They did not last long. Next came the Romantics. These created the "Knights of the Skies" legends: the lone hunter, mano-a-mano duels at 10,000, and chivalrous Udet-Guynemer gestures. They were quickly superceded by the Professionals to whom flying was a job and group tactics became the order of the day."
The author [might have been Charles Gibbs-Smith] cited von Richtofen as the very embodiment of the Professionals. There was nothing flashy about him or his flying. You'd think that with 80 kills, there'd be a host of stories about his encounters, but the only one I've heard much about is his duel with Lanoe Hawker. He did not seek a white-knuckle flying, look-your-opponent-in-the-eye encounter. The Professionals came to the realization that only a jerk seeks a fair fight.
So if we could set up a one-on-one with a Voss, Mannoick or a Rickenbacker, MvR might easily come off second best.